For Windows XP, just use the TCP Optimizer. Even with the slider at 20Mbps, the RWIN buffer should be able to handle up to 100Mbps provided the latency is not excessive.
For Vista / Windows 7 you'd have to read this: http://www.speedguide.net/read_articles.php?id=2574 ... There is also a patch you can use. For 100Mbps, you may want to set the "autotunninglevel" to "experimental", that allows for very large TCP Window values.
Remember that non-business lines are usually shared between users, especially on cable. The bottleneck may not be your end of the connection. Even if Shaw can provide 100Mbps for every user currently using the line, there are few servers that can handle 100Mbps per client.
A TCP Analyzer report can show your current settings, as seen from servers.
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