Pretty simple. Setup the wired network to be some IP range, say 192.168.0.x, and the wired to be another, say 10.0.0.x. Then give the wired connections an IP address in the wired range, subnet mask, and DNS server, but NO default gateway. Give wireless IP, subnet, default gateway, DNS.
Now when the computer looks to send something to an unknown address its only choice is the connection with a default gateay. So all internet traffic is by definition off of your network (unknown) and is forced through wireless.
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